Simultaneous Selective Area Growth of Wurtzite and Zincblende Self-Catalyzed GaAs Nanowires on Silicon
نویسندگان
چکیده
Selective area epitaxy constitutes a mainstream method to obtain reproducible nanomaterials. As counterpart, self-assembly allows their growth without costly substrate preparation, with the drawback of uncontrolled positioning. We propose mixed approach in which is limited reduced regions on patterned silicon substrate. While nanowires grow wide distribution diameters, we note mostly binary occurrence crystal phases. Self-catalyzed GaAs form either wurtzite or zincblende phase same run. Quite surprisingly, thicker are and thinner zincblende, while common view predicts reverse trend. relate this phenomenon influx Ga adatoms by surface diffusion, results different contact angles droplets. demonstrate thick NWs up 200 nm diameter Au-free approach, has not been achieved so far our knowledge.
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ژورنال
عنوان ژورنال: Nano Letters
سال: 2021
ISSN: ['1530-6992', '1530-6984']
DOI: https://doi.org/10.1021/acs.nanolett.1c00349